European Union foreign ministers agreed on Wednesday (Sep 21) to prepare new sanctions on Russia and increase weapons' deliveries to Kyiv after President Vladimir Putin ordered the country's first wartime mobilisation since World War II to fight in Ukraine.

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The bloc's 27 foreign ministers are in New York for the annual gathering of world leaders at the United Nations.

EU foreign policy chief Josep Borrell said Putin's announcement - which included moves to annex swaths of Ukrainian territory and a threat to use nuclear weapons to defend Russia - showed panic and desperation.

"It's clear that Putin is trying to destroy Ukraine," Borrell told reporters after ministers met to decide how to respond.

After being briefed by Ukrainian Foreign Minister Dmytro Kuleba, the ministers agreed to task their teams to prepare an eighth sanctions package that would target "more relevant sectors of the Russian economy and continue targeting people responsible for the war of aggression in Ukraine", Borrell said.

EU ministers will hold their next formal meeting in mid-October when a sanctions package could be formalised.

The ministers also agreed to ramp up weapons supplies to Ukraine. Borrell declined to give further details on the type of sanctions or military support, but said he believed there would be "unanimous" support within the bloc for new measures.